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KMID : 0043319930160020152
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Archives of Pharmacal Research
1993 Volume.16 No. 2 p.152 ~ p.154
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Hofmann Rearrangement by Using N-bromophthalimide-Silveracetate in DMF
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Park Min-Soo
Choi Chang-Uk
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Abstract
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By using N-bromophthalimide (NBP) as halonium ion source for the Hofmann rearrangement, a series of primary amide could be ocnverted to the corresponding cabamate in excellent yields. So NBP was throught to be very effective and practical halonium ion source for the Hofmann rearrangement.
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KEYWORD
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N-bromophthalimide, N-bromosuccinimide, Dibromantine, Hofmann rearragement, Primary amide, Carbamate, Halonium ion
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